Pd-Catalyzed Allylic C-H Activation to Seven-Membered N,O-Heterocycles
| Autor: | Alvaro Velasco Rubio, CDMF FAPESP, Jesús A. Varela, Carlos Saa |
|---|---|
| Přispěvatelé: | Universidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Moleculares, Universidade de Santiago de Compostela. Departamento de Química Orgánica |
| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
Allylic rearrangement
1 4-Benzoxazepines Metals and Alloys European Regional Development Fund Library science 1 4-Oxazepanes General Chemistry N O-Heterocycles Catalysis C-H Activation Surfaces Coatings and Films Electronic Optical and Magnetic Materials Political science Materials Chemistry Ceramics and Composites media_common.cataloged_instance European union 1 4-Benzodiazepinones Palladium media_common Accreditation |
| Zdroj: | Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela instname |
| Popis: | Pd-catalyzed allylic C-H activation of simple olefins allows an easy entry to seven-membered N,O-heterocycles such as 1,4-benzoxazepines (1,4-BZOs), 1,4-benzodiazepinones (1,4-BZDs) and 1,4-oxazepanes in good to excellent yields. Straightforward derivatizations of the olefinated 1,4-BZO shows the synthetic utility of this methodology. We acknowledge financial support from MINECO (project CTQ2017-87939R and ORFEO-CINQA network RED2018-102387-T), the Xunta de Galicia (project ED431C 2018/04 and Centro singular de investigación de Galicia accreditation 2019-2022, ED431G 2019/03) and the European Union (European Regional Development Fund – RDF). A.V.-R. thanks Xunta de Galicia for a predoctoral fellowship (ED481A-2018/34, 2018-2021) SI |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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