A Photochemical Strategy for Carbon Isotope Exchange with CO 2
| Autor: | Antoine Sallustrau, Charles S. Elmore, Gianluca Destro, Alexandre Labiche, Victor Babin, Alex Talbot, Frédéric Taran, Antonio Del Vecchio, Davide Audisio |
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| Přispěvatelé: | Direction de Recherche Fondamentale (CEA) (DRF (CEA)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA), AstraZeneca |
| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
Decarboxylation
Carbon-14 010402 general chemistry Photochemistry 01 natural sciences 7. Clean energy Catalysis chemistry.chemical_compound Primary (chemistry) 010405 organic chemistry [CHIM.ORGA]Chemical Sciences/Organic chemistry Photoredox catalysis General Chemistry [CHIM.CATA]Chemical Sciences/Catalysis 0104 chemical sciences chemistry Carbon dioxide Isotopes of carbon Photocatalysis [CHIM.RADIO]Chemical Sciences/Radiochemistry Isotope labeling |
| Zdroj: | ACS Catalysis ACS Catalysis, 2021, 11 (5), pp.2968-2976. ⟨10.1021/acscatal.0c05344⟩ ACS Catalysis, American Chemical Society, 2021, 11 (5), pp.2968-2976. ⟨10.1021/acscatal.0c05344⟩ |
| ISSN: | 2155-5435 |
| Popis: | International audience; A photocatalytic approach for carbon isotope exchange is reported. Utilizing [ 13 C]CO2 and [ 14 C]CO2 as primary C1 sources, this protocol allows the insertion of the desired carbon isotope into phenyl acetic acids without the need of structural modifications or prefunctionalization, in one single step. The exceptionally mild conditions required for this traceless transformation are in stark contrast with previous methods requiring the use of harsh thermal conditions. |
| Databáze: | OpenAIRE |
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