Coronene-Containing N-Heteroarenes: 13 Rings in a Row
| Autor: | Manuel Schaffroth, Frank Rominger, Fabian Paulus, Hilmar Reiss, Hubert Wadepohl, Alexander H. Endres, Uwe H. F. Bunz, Roland Krämer |
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| Rok vydání: | 2016 |
| Předmět: |
Fabrication
010405 organic chemistry business.industry Modular system Transistor Nanotechnology General Chemistry Electron Modular design 010402 general chemistry 01 natural sciences Biochemistry Catalysis Coronene 0104 chemical sciences law.invention chemistry.chemical_compound Colloid and Surface Chemistry chemistry law Optoelectronics Crystallite business Electronic properties |
| Zdroj: | Journal of the American Chemical Society. 138:1792-1795 |
| ISSN: | 1520-5126 0002-7863 |
| DOI: | 10.1021/jacs.5b12642 |
| Popis: | We describe the modular synthesis of three novel large N-heteroarenes, containing 9, 11, and 13 annulated rings. This modular system features fused azaacene units to a coronene nucleus. We evaluate the optical and electronic properties and the solid-state packing of the targets. The electronic properties of the 13-ring N-heteroarene allow the fabrication of a proof-of-concept thin-film transistor. Electron mobilities up to 8 × 10(-4) cm/(V s) were obtained for polycrystalline films. |
| Databáze: | OpenAIRE |
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