Semi-Crystalline Polyesters Based on a Novel Renewable Building Block
| Autor: | CE Cor Koning, Jacco van Haveren, Pieter Eduard, Shanmugam Thiyagarajan, Célia Fonseca Guerra, Daan S. van Es, Jing Wu, Artur Rozanski, Lidia Jasinska-Walc, Bart A. J. Noordover |
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| Přispěvatelé: | Theoretical Chemistry, Organic Chemistry, AIMMS, Chemical Engineering and Chemistry |
| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: |
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4/3 6-dianhydrohexitols Isosorbide Materials science Polymers and Plastics crystallization isosorbide melting behavior 4/3 chemistry Inorganic Chemistry chemistry.chemical_compound Differential scanning calorimetry poly(butylene terephthalate) BBP Sustainable Chemistry & Technology Polymer chemistry Materials Chemistry medicine succinic acid Carboxylate Biobased Products SDG 7 - Affordable and Clean Energy polymers chemistry.chemical_classification 6-dianhydrohexitols Organic Chemistry Polymer coating applications Polyester Dicarboxylic acid Polymerization Glass transition resources SDG 6 - Clean Water and Sanitation SDG 7 – Betaalbare en schone energie medicine.drug |
| Zdroj: | Macromolecules, 45, 5069-5080. American Chemical Society Macromolecules 45 (2012) 12 Macromolecules, 45(12), 5069-5080. American Chemical Society Wu, J, Eduard, P, Thiyagarajan, S, Jasinska-Walc, L, Rozanski, A, Fonseca Guerra, C, Noordover, B A J, van Haveren, J, van Es, D S & Koning, C E 2012, ' Semi-Crystalline Polyesters Based on a Novel Renewable Building Block ', Macromolecules, vol. 45, pp. 5069-5080 . https://doi.org/10.1021/ma300782h Macromolecules, 45(12), 5069-5080 |
| ISSN: | 0024-9297 |
| Popis: | Isohexides, like e.g. isosorbide, are well-known carbohydrate-based rigid diols which are capable of dramatically increasing the glass transition temperature of polyesters. However, their relatively low reactivity has thus far hampered large-scale industrial applications in the polymer field. Recently, with the aim to increase reactivity while at the same time retain rigidity, we have developed a new isoidide dicarboxylic acid (IIDCA) by transforming the secondary hydroxyls into carboxylate functionalities. Here we report the first polymers based on IIDCA and linear α,ω-diols. The novel polyesters were obtained via melt polymerization and exhibited weight-average molecular weights in the range of 13 000-34 000 g/mol and polydispersities close to 2.0. NMR analyses showed that the exo-exo configuration of the isoidide dicarboxylate units was preserved during synthesis. Both differential scanning calorimetry and wide-angle X-ray diffraction analyses showed that the IIDCA polyesters are semicrystalline materials. A systematic study on structure-thermal properties relations among relevant series of polyesters, such as isomeric polymers based on isoidide, revealed several interesting differences in melting and glass transition temperatures, which are thought to be related to variations in chain packing and free volume. © 2012 American Chemical Society. |
| Databáze: | OpenAIRE |
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