Novel aerobic oxidation of primary sulfones to carboxylic acids
| Autor: | Ryan K. Murphy, S. Shaun Murphree, Daniel J. Mastarone, Bettina M. Panseri, Matthew P. Betush, Amy C. Bonaparte |
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| Rok vydání: | 2011 |
| Předmět: |
chemistry.chemical_classification
Primary (chemistry) Atmospheric oxygen Molecular Structure Aryl Organic Chemistry Carboxylic Acids Biochemistry Oxygen chemistry.chemical_compound Deprotonation chemistry Yield (chemistry) Organic chemistry Sulfones Physical and Theoretical Chemistry Oxidation-Reduction Alkyl |
| Zdroj: | Organic letters. 13(6) |
| ISSN: | 1523-7052 |
| Popis: | Primary alkyl aryl sulfones are converted to the corresponding carboxylic acids in fair to excellent yield through double deprotonation and exposure to atmospheric oxygen. The methodology allows for the convenient synthesis of (13)C labeled carboxylic acids. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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