Fast Palladium Catalyzed Arylation of Alkenes Using Bulky Monodentate Phosphorus Ligands

Autor:	Maarten D. K. Boele, Paul C. J. Kamer, Johannes G. de Vries, Piet W. N. M. van Leeuwen, Gino P. F. van Strijdonck
Přispěvatelé:	Stratingh Institute of Chemistry
Jazyk:	angličtina
Rok vydání:	1999
Předmět:	chemistry.chemical_classification Denticity Chemistry Alkene Migratory insertion chemistry.chemical_element Rate-determining step Photochemistry Oxidative addition Combinatorial chemistry Catalysis Inorganic Chemistry Heck reaction Palladium
Zdroj:	European Journal of Inorganic Chemistry, 1999(7). WILEY-V C H VERLAG GMBH
ISSN:	1434-1948
DOI:	10.1002/(SICI)1099-0682(199907)1999:7<1073::AID-EJIC1073>3.0.CO;2-T
Popis:	Complex 1b shows an unprecedented high activity in the Heck reaction. Kinetic studies show that in this system not the oxidative addition but the alkene coordination/migratory insertion is the rate determining step.
Databáze:	OpenAIRE
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