catena-Poly[[bis(1H-indole-5-carboxylato-κ2 O,O′)zinc(II)]-μ-4,4′-azobipyridine-κ2 N 1:N 1′]
| Autor: | J.S. Nirmal Ram, Sundaramoorthy Gomathi, I. Abdul Razak, S. Jegan Jennifer, U. Sathya |
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| Rok vydání: | 2021 |
| Předmět: |
chemistry.chemical_classification
crystal structure Crystallography Denticity Ligand Coordination polymer Crystal structure metal-organic framework 010402 general chemistry 010403 inorganic & nuclear chemistry Crystal engineering 01 natural sciences structural chemistry 0104 chemical sciences coordination polymer chemistry.chemical_compound non-covalent interactions chemistry crystal engineering QD901-999 Pyridine Non-covalent interactions Metal-organic framework |
| Zdroj: | IUCrData, Vol 6, Iss 5, p x210522 (2021) |
| ISSN: | 2414-3146 |
| DOI: | 10.1107/s2414314621005228 |
| Popis: | The asymmetric unit of the title coordination polymer [Zn(C9H6NO2)2(C10H8N4)] n , consists of one ZnII cation, one bidentate 1H-indole-5-carboxylate (I5C) anion and half of a 4,4′-azobipyridine (Abpy) neutral ligand. In the coordination polyhedron, the ZnII ion adopts a distorted octahedral geometry. The coordination polymer is stabilized by a combination of N—H...O and C—H...π interactions, which leads to the formation of wave-like two-dimensional coordination polymeric layers. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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