Large-scale synthesis of high quality InP quantum dots in a continuous flow-reactor under supercritical conditions
| Autor: | Stefan Kröpke, Christian Ippen, Andreas Holländer, Tonino Greco, Benjamin Schneider, Christopher Pries |
|---|---|
| Přispěvatelé: | Publica |
| Rok vydání: | 2015 |
| Předmět: |
Materials science
Photoluminescence Mechanical Engineering Analytical chemistry Bioengineering General Chemistry Toluene Supercritical fluid chemistry.chemical_compound Full width at half maximum chemistry Mechanics of Materials Quantum dot Octadecene Indium phosphide General Materials Science Electrical and Electronic Engineering Quantum |
| Zdroj: | Nanotechnology. 26(8) |
| ISSN: | 1361-6528 |
| Popis: | The synthesis of indium phosphide quantum dots (QDs) in toluene under supercritical conditions was carried out in a macroscopic continuous flow reaction system. The results of first experiments are reported in comparison with analogous reactions in octadecene. The reaction system is described and details are provided about special procedures that are enabled by the continuous flow system for the screening of reaction conditions. The produced QDs show very narrow emission peaks with full width at half maximum down to 45 nm and reasonable photoluminescence quantum yields. The subsequent purification process is facilitated by the ease of removal of toluene, and the productivity of the system is increased by high temperature and high pressure conditions. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|