Crystal structure of 2,4-bis(ethylthio)-2,4-dithioxo-1,3,2,4-dithiadiphosphetane, (C2H5S)2(P2S2)S2

Autor:	M. Ystenes, V. Kaiser, Wolfgang Brockner, Frank Menzel
Rok vydání:	1993
Předmět:	Stereochemistry Crystal structure Triclinic crystal system Condensed Matter Physics Ring (chemistry) Ion Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Covalent bond Molecule General Materials Science Derivative (chemistry)
Zdroj:	Zeitschrift für Kristallographie - Crystalline Materials. 207:306-307
ISSN:	2196-7105 2194-4946
DOI:	10.1524/zkri.1993.207.part-2.306
Popis:	Triclinic P1, a=6.276, b=7.262, c=10.200A, α=89.81, β=911.26, γ=93.52°, Z=1, R=0.071. The crystal structure of the Davy-reagent-methyl shows the molecule structure as a derivative of the hexathiometadiphosphate anion P 2 S 6 2- with covalent bonded methyl groups. The position of the ligands close to the P 2 S 2 -ring is not an effect of the size of the ligands. The much larger p-tolyl group is orientated in an equivalent way close to the P 2 S 2 -ring
Databáze:	OpenAIRE
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