Cyclophosphorylation of polyphenols by diamidoarylphosphites

Autor:	Larisa K. Vasyanina, Maria V. Dyagileva, Wolf D. Habicher, Ingmar Bauer, Roman V. Merkulov, Mikhail Yu. Antipin, Vera I. Maslennikova, Konstantin A. Lyssenko, Dirk Weber, Eduard E. Nifantyev
Rok vydání:	2003
Předmět:	Stereochemistry Organic Chemistry General Medicine Biochemistry Medicinal chemistry chemistry.chemical_compound chemistry Group (periodic table) Polyphenol Drug Discovery Calixarene Phosphorylation Reactivity (chemistry) Phenols Reaction site
Zdroj:	Tetrahedron. 59:1753-1761
ISSN:	0040-4020
Popis:	It was found that the cyclophosphorylation of polyphenols by diamidoarylphosphites proceeds via the rupture of only one P–N bond and one P–O bond, the second P–N bond remaining intact. It is supposed that the unusual lack of reactivity of the P–N bond is due to the spatial arrangement of the amido group with respect to the reaction site in phosphorylated intermediates 5 .
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4d82b399d2656d6e63591e05b6d00e1c https://doi.org/10.1016/s0040-4020(03)00111-x Zobrazit plný text záznamu Full Text from ScienceDirect