Catalytic Enantioselective Synthesis of Planar-Chiral Cyclic Amides Based on a Pd-Catalyzed Asymmetric Allylic Substitution Reaction
| Autor: | Nobumasa Ichikawa, Kazunobu Igawa, Keisuke Katanoda, Katsuhiko Tomooka, Yusuke Ano, Toshiyuki Akiyama, Masato Ito |
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| Rok vydání: | 2015 |
| Předmět: |
inorganic chemicals
Substitution reaction Allylic rearrangement Chemistry organic chemicals Chiral ligand technology industry and agriculture Enantioselective synthesis General Chemistry Biochemistry Combinatorial chemistry Catalysis Colloid and Surface Chemistry polycyclic compounds Organic chemistry heterocyclic compounds |
| Zdroj: | Journal of the American Chemical Society. 137:7294-7297 |
| ISSN: | 1520-5126 0002-7863 |
| DOI: | 10.1021/jacs.5b04340 |
| Popis: | The highly enantioselective synthesis of planar-chiral nine-membered cyclic amides was achieved by the Pd-catalyzed asymmetric allylic cyclization of achiral linear precursors in the presence of a catalytic amount of chiral ligand. |
| Databáze: | OpenAIRE |
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