Extraction of alkali metal, magnesium and calcium ions with cyclopentadienyltris(diethylphosphito-P)cobaltate(−1)

Autor:	Erhard Uhlemann, H. Bukowsky, W. Kläui
Rok vydání:	1996
Předmět:	Chemistry Ligand Magnesium Sodium Potassium Inorganic chemistry chemistry.chemical_element Alkali metal Biochemistry Analytical Chemistry Stability constants of complexes Institut für Chemie Environmental Chemistry Lithium Qualitative inorganic analysis Spectroscopy
Zdroj:	Analytica Chimica Acta. 319:271-274
ISSN:	0003-2670
DOI:	10.1016/0003-2670(95)00491-2
Popis:	The extraction of lithium, sodium, potassium, magnesium and calcium ions with the oxygen tripod ligand cyclopentadienyltris (diethylphosphito-P)cobaltate(−1), [(C 5 H 5 )Co{P(O)(OC 2 H 5 ) 2 } 3 ] − has been studied as a function of pH and ligand concentration.Li + could be successfully separated from Na + and K + . The separation of Li + from fCa 2+ and Mg 2+ was achieved by masking Mg 2+ and Ca 2+ with EDTA or by precipitating them with the ligand before Li extraction. The composition and stability constants have been determined for the complexes of Li + , Mg 2+ , and Ca 2+ .
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4cf53655650b0c31addfdd81513b251c https://doi.org/10.1016/0003-2670(95)00491-2 Zobrazit plný text záznamu Full Text from ScienceDirect