Probing the chemical state of tin oxide NP catalysts during CO2 electroreduction: A complementary operando approach
| Autor: | Beatriz Roldan Cuenya, Peter Broekmann, Ilya Sinev, Motiar Rahaman, Veerabhadrarao Kaliginedi, Mahdi Ahmadi, Abhijit Dutta, Soma Vesztergom, Akiyoshi Kuzume |
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| Rok vydání: | 2018 |
| Předmět: |
X-ray absorption spectroscopy
Materials science Absorption spectroscopy Renewable Energy Sustainability and the Environment Inorganic chemistry Oxide 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Catalysis Reaction rate symbols.namesake chemistry.chemical_compound Chemical state chemistry Standard electrode potential symbols General Materials Science Electrical and Electronic Engineering 0210 nano-technology Raman spectroscopy |
| Zdroj: | Nano Energy. 53:828-840 |
| ISSN: | 2211-2855 |
| DOI: | 10.1016/j.nanoen.2018.09.033 |
| Popis: | In this paper we combine two operando methods, Raman spectroscopy and X-ray absorption spectroscopy (XAS), in order to probe reduced graphene-oxide supported tinIV oxide nanoparticles ( SnO 2 NPs @ rGO ) as they are being used to catalyse CO2 electroreduction. To achieve high reaction rates it is necessary to apply sufficiently cathodic electrode potentials. Under such conditions, however, not only CO2 is reduced electrochemically, but also the catalyst particles may be transformed from the initial SnIV state to SnII or, in an extreme case, to metallic Sn. While SnII species still favour CO2 electroreduction, yielding formate as a primary product, on metallic Sn CO2 reduction is disfavoured with respect to the competing hydrogen evolution reaction (HER). We show that operando XAS, a robust technique yielding information averaged over a large surface area and a relatively large thickness of the catalyst layer, is a very expedient method able to detect the reduction of SnO 2 NPs @ rGO to metallic Sn. XAS can thus be used to establish an optimum potential for the electroreduction in practical electrolysing cells. It takes, however, a complementary method offered by operando Raman spectroscopy, having greater sensitivity at the catalyst/electrolyte solution interface, to probe reduction intermediates such as the SnII state, which remain undetectable for ex situ methods. As it is shown in the paper, Raman spectroscopy may also find further use when investigating the recovery of catalyst particles following exposure to extreme reducing conditions. |
| Databáze: | OpenAIRE |
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