New 2-o-methylrhamno-isoflavones fromStreptomycessp

Autor: Susanne Grabley, Ralf Thiericke, Dirk Wunderlich, Isabel Sattler, Xiao-Zhang Feng, Jin-Feng Hu
Rok vydání: 2003
Předmět:
Zdroj: Natural Product Research. 17:451-458
ISSN: 1478-6427
1478-6419
Popis: Chemical screening with extracts of Actinomycetes strains resulted in the detection, isolation and structure elucidation of five new isoflavone glycosides from Streptomyces sp. (GT 51173): 5-O-alpha-L-rhamnopyranosyl genestein (genestein G1, 1), 5-O-alpha-L-rhamnopyranosyl-7-O-[2-O-(methyl)-alpha-L-rhamnopyranosyl] genestein (genestein G2, 2), 7,4'-O-di-[2-O-(methyl)-alpha-L-rhamnopyranosyl] daidzein (daidzein G1, 3), 6-O-methyl-7-O-[2-O-(methyl)-alpha-L-rhamnopyranosyl] daidzein (daidzein G2, 4) and 7-O-[2-O-(methyl)-alpha-L-rhamnopyranosyl] daidzein (daidzein G3, 5). As a striking structural feature, 2-5 bear one or two alpha-L-rhamnopyranosyl sugar moieties with methoxy groups in an axial position at C-2.
Databáze: OpenAIRE