Chiral N-heterocyclic carbene catalyzed annulation of α,β-unsaturated aldehydes with 1,3-dicarbonyls

Autor:	Ning-Fei Jiang, Xingliang Zheng, Zhi-Qiang Zhu, Ji-Chang Xiao, Xiaolong Wan
Rok vydání:	2011
Předmět:	Annulation Metals and Alloys Enantioselective synthesis Substrate (chemistry) General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Materials Chemistry Ceramics and Composites Organic chemistry Carbene
Zdroj:	Chemical communications (Cambridge, England). 47(30)
ISSN:	1364-548X
Popis:	Chiral N-heterocyclic carbene catalyzed annulations of ynals and enals with 1,3-dicarbonyls have been described. The two reactions provided direct and efficient methods for enantioselective synthesis of functionalized dihydropyranones. Comparatively, the reactions starting from ynals were atom-economical; furthermore the reactions of enals demonstrated broader substrate compatibility.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4c78883a016402dcb672b7d83e1c6369 https://pubmed.ncbi.nlm.nih.gov/21709880 Zobrazit plný text záznamu