Novel Spiro-Configured PET Chromophores Incorporating 4,5-Diazafluorene Moiety as an Electron Acceptor

Autor:	Ken-Tsung Wong, Fu-Chuan Fang, Hsiao-Fan Chen
Rok vydání:	2006
Předmět:	chemistry.chemical_classification Chemistry Aryl Organic Chemistry Electron acceptor Chromophore Photochemistry Biochemistry Metal chemistry.chemical_compound visual_art visual_art.visual_art_medium Moiety Physical and Theoretical Chemistry
Zdroj:	Organic Letters. 8:3501-3504
ISSN:	1523-7052 1523-7060
DOI:	10.1021/ol061227n
Popis:	[reaction: see text] We have synthesized novel spiro-bridged chromophores incorporating a 4,5-diazafluorene unit as the electron acceptor (A) and aryl amino groups as donor (D) moieties. The orthogonal D-A configuration limits ground-state D-A interactions but allows efficient PET reactions. The PET efficiency was modulated by the electronic characteristics of the donor and by the D-A distance. Preliminary studies showed that the PET process can be manipulated through metal ion complexation of the 4,5-diazafluorene moiety.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4c6da939df5d1e1a6efd4ed2a73dcb09 https://doi.org/10.1021/ol061227n Zobrazit plný text záznamu