The electronic spectrum of AuO: a combined theoretical and experimental study

Autor: L. C. O'Brien, Björn O. Roos, and Anne E. Oberlink
Rok vydání: 2006
Předmět:
Zdroj: The journal of physical chemistry. A. 110(43)
ISSN: 1089-5639
Popis: The near-infrared electronic spectrum of AuO1 has been re-examined in light of the new microwave data on the nu = 0 and nu = 1 vibrations of the X-2 Pi(3/2) state of AuO. The two observed bands in the spectrum, with red-degraded bandheads located at 10726 and 10665 cm(-1), have been reanalyzed. New theoretical work on AuO clarifies the electronic structure, and the bands in the infrared are now assigned as the (0,1) and (1,2) bands of the a(4)Sigma(-)(3/2) - X-2 Pi(3/2) transition, respectively.
Databáze: OpenAIRE