Effect of the chain lengthening on transport properties of imidazolium-based ionic liquids
| Autor: | Nesrine Chaabene, Rita Khalil, Mirella Azar, Ibrahim Bou Malham, Mireille Turmine |
|---|---|
| Přispěvatelé: | Laboratoire Interfaces et Systèmes Electrochimiques (LISE), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Laboratoire Energétique et Réactivité à l'Echelle Nanométrique [Université libanaise] (EREN ), Université Libanaise |
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
General Chemical Engineering
Diffusion General Physics and Astronomy 02 engineering and technology 010402 general chemistry Electrochemistry 01 natural sciences Ion Viscosity chemistry.chemical_compound Ionic conductivity [CHIM]Chemical Sciences Physical and Theoretical Chemistry diffusion coefficient Alkyl ionic liquid chemistry.chemical_classification ferrocenemethanol Ionic-liquid imidazolium 021001 nanoscience & nanotechnology 0104 chemical sciences chemistry Ionic liquid Physical chemistry Cyclic voltammetry 0210 nano-technology |
| Zdroj: | Fluid Phase Equilibria Fluid Phase Equilibria, Elsevier, 2020, 503, 112316 (7p.). ⟨10.1016/j.fluid.2019.112316⟩ |
| ISSN: | 0378-3812 |
| DOI: | 10.1016/j.fluid.2019.112316⟩ |
| Popis: | International audience; The objective of this work is to study the effect of the lengthening of the linear alkyl chain of the imidazolium cation on some transport properties. We focused on hydrophobic ionic liquids based on bis(trifluoromethanesulfonyl)imide anion. Among the different properties, we measured at the viscosity and ionic conductivity of four different 1-alkyl-3-methylimidazolium ionic liquid in the temperature range between 293 and 333K. Thus, Electrochemical windows of these ionic liquids and the diffusion coefficient of ferrocenemethanol (FcMeOH) in the four ionic liquids were studied using cyclic voltammetry at 298K. The FcMeOH diffusion coefficient was found to be higher in shorter alkyl chain ionic liquids. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect