| Autor: |
Abhishek Banerjee, Ulrich Kortz, Natalya V. Izarova |
| Rok vydání: |
2011 |
| Předmět: |
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| Zdroj: |
Inorganic chemistry. 50(20) |
| ISSN: |
1520-510X |
| Popis: |
We have prepared the three novel Pd(II)-containing tungstophosphates [Pd(2)(α-PW(11)O(39)H(0.5))(2)](9-) and two structural isomers of [Pd(2)(α(2)-P(2)W(17)O(61)H(n))(2)]((16-2n)-) via simple synthetic procedures and characterized their potassium salts by single-crystal X-ray diffraction, elemental analysis, and IR and multinuclear ((31)P and (183)W) NMR spectroscopy. This study sheds light on the long-standing question about the nature and structure of the actual products formed in the reaction of Pd(II) ions with monolacunary Keggin-type [α-XW(11)O(39)](n-) and Wells-Dawson-type [α(2)-P(2)W(17)O(61)](10-) heteropolytungstates. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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