Bright Fluorescence and Host-Guest Sensing with a Nanoscale M4L6Tetrahedron Accessed by Self-Assembly of Zinc-Imine Chelate Vertices and Perylene Bisimide Edges

Autor:	Peter D. Frischmann, Valentin Kunz, Frank Würthner
Rok vydání:	2015
Předmět:	Imine Supramolecular chemistry Quantum yield General Medicine General Chemistry Chromophore Photochemistry Fluorescence Catalysis Coronene chemistry.chemical_compound chemistry Luminescence Perylene
Zdroj:	Angewandte Chemie International Edition. 54:7285-7289
ISSN:	1433-7851
Popis:	A highly luminescent Zn4L6 tetrahedron is reported with 3.8 nm perylene bisimide edges and hexadentate ZnII–imine chelate vertices. Replacing FeII and monoamines commonly utilized in subcomponent self-assembly with ZnII and tris(2-aminoethyl)amine provides access to a metallosupramolecular host with the rare combination of structural integrity at concentrations
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4bd2e839cc06692ed33959fe4747122f https://doi.org/10.1002/anie.201501670 Zobrazit plný text záznamu Plný text