Development and application of SBA‐15 assisted electromembrane extraction followed by corona discharge ion mobility spectrometry for the determination of Thiabendazole in fruit juice samples

Autor:	Ali Reza Fakhari, Mohammadreza Mohammadi Nilash, Fahimeh Mirzaei
Rok vydání:	2019
Předmět:	Analyte Ion-mobility spectrometry Filtration and Separation 02 engineering and technology 01 natural sciences Analytical Chemistry chemistry.chemical_compound Limit of Detection Thiabendazole Animals Sample preparation Pesticides Corona discharge Detection limit Chromatography Chemistry 010401 analytical chemistry Extraction (chemistry) Membranes Artificial Electrochemical Techniques Silicon Dioxide 021001 nanoscience & nanotechnology 0104 chemical sciences Fruit and Vegetable Juices Silanol Membrane 0210 nano-technology
Zdroj:	Journal of Separation Science. 42:1786-1793
ISSN:	1615-9314 1615-9306
DOI:	10.1002/jssc.201800676
Popis:	A new sample preparation method based on SBA-15 assisted electromembrane extraction coupled with corona discharge ion mobility spectrometer was developed for the determination of Thiabendazole as a model basic pesticide in fruit juice samples. The addition of SBA-15 in the supported liquid membrane in electromembrane extraction system not only can lead to enhancement of the effective surface area, but also introducing the negatively charged silanol groups into supported liquid membrane might improve migration of positively charged analytes toward the supported liquid membrane and finally into the acceptor solution. To investigate the effect of the presence of SBA-15 in the supported liquid membrane on the extraction efficiency, a comparative study was carried out between the conventional electromembrane extraction and SBA-15/electromembrane extraction methods. Under the optimized conditions, SBA-15/electromembrane extraction method showed higher extraction efficiencies in comparison with conventional electromembrane extraction method. SBA-15/electromembrane extraction method exhibited a low limit of detection (0.9 ng/mL), high preconcentration factor (167) and high recovery (83%). Finally, the applicability of SBA-15/electromembrane extraction method was studied by the extraction and determination of Thiabendazole as a model basic pesticide in fruit juice samples.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4bb82929d60afa0a5b27d0f049279d75 https://doi.org/10.1002/jssc.201800676 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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