Recent Synthetic Applications of Manganese in Organic Synthesis

Autor:	Jose M. Concellon, Vicente del Amo, Humberto Rodriguez‐Solla
Rok vydání:	2008
Předmět:	chemistry.chemical_compound Transmetalation chemistry Metalation Organic Chemistry High selectivity chemistry.chemical_element Organic chemistry Organic synthesis General Chemistry Manganese Catalysis Group 2 organometallic chemistry
Zdroj:	Chemistry - A European Journal. 14:10184-10191
ISSN:	1521-3765 0947-6539
Popis:	While the organometallic compounds derived from many metals have found a broad application in organic synthesis, the use of organomanganese compounds has only recently been developed due to the passivity exhibited by commercial Mn in the direct metalation of organic compounds. In this Concept article, we highlight the potential of manganese and its organometallic compounds in organic synthesis by illustration of the studies previously reported by others and our laboratory in this field. Based on the transformations reported herein, organomanganese compounds could become important tools in the future of the organic synthesis, due to their high selectivity.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4b9bb9067fbfb6ac89c51142d65411d1 https://doi.org/10.1002/chem.200800796 Zobrazit plný text záznamu Plný text