Fabrication of new type of barium ferrite/copper oxide composite nanoparticles blended polyvinylchloride based heterogeneous ion exchange membrane
| Autor: | Alireza Salabat, A. Ahmadi, Sayed Mohsen Hosseini, N. Rafiei |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
Copper oxide
Ion exchange Scanning electron microscope General Chemical Engineering 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Electrochemistry 01 natural sciences 0104 chemical sciences law.invention lcsh:Chemistry chemistry.chemical_compound Membrane lcsh:QD1-999 chemistry Chemical engineering Optical microscope law Fourier transform infrared spectroscopy 0210 nano-technology Barium ferrite |
| Zdroj: | Arabian Journal of Chemistry, Vol 13, Iss 1, Pp 2470-2482 (2020) |
| ISSN: | 1878-5352 |
| Popis: | The current study focuses on the electrochemical, morphological and antibacterial characteristics of a new type of polyvinylchloride based cation exchange membrane modified by BaFe12O19/CuO composite nanoparticles. The used BaFe12O19/CuO composite nanoparticles were synthesized by chemical precipitation technique. The formation of BaFe12O19/CuO was characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and X-ray diffraction (XRD). SEM and scanning optical microscopy (SOM) images also showed relatively uniform structure for the prepared membranes. The membrane water uptake was enhanced up to 14.5% in presence of BaFe12O19/CuO composite nanoparticles. The membrane ion exchange capacity, membrane potential, transport number, surface charge density, permselectivity and ion permeability/flux were also improved sharply by increase of additive concentration up to 2 wt% and then showed decreasing trend by more BaFe12O19/CuO content ratio from 2 to 8 wt%. The membrane areal electrical resistance were decreased significantly from ∼24 to ∼5 (Ω cm2) by using of BaFe12O19/CuO nanoparticles. Moreover, modified membranes demonstrated good ability to removal of E-coli bacteria. Keywords: Cation exchange membrane, BaFe12O19/CuO nanoparticles, Chemical precipitation, Electrochemical properties, Antibacterial characteristic |
| Databáze: | OpenAIRE |
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