Synthesis of novel salts with HF, AsF3 and XeF2 as ligands to metal cations
| Autor: | Melita Tramšek, Boris Zemva |
|---|---|
| Rok vydání: | 2006 |
| Předmět: |
chemistry.chemical_classification
Chemistry Organic Chemistry Inorganic chemistry Structural diversity General Medicine Biochemistry Medicinal chemistry Ion Coordination complex Inorganic Chemistry Metal symbols.namesake Group (periodic table) Oxidation state visual_art Polymer chemistry visual_art.visual_art_medium symbols Environmental Chemistry Physical and Theoretical Chemistry Raman spectroscopy |
| Zdroj: | Journal of Fluorine Chemistry. 127:1275-1284 |
| ISSN: | 0022-1139 |
| DOI: | 10.1016/j.jfluchem.2006.05.014 |
| Popis: | A review of all known compounds of the type [Mn(L)m](AF6)n (M is a metal in the oxidation state n; A = P, As, Sb and Bi; L = HF, AsF3 and XeF2) is given with the emphasis on the compounds isolated and characterized by our group. The synthetic routes for the preparation of these compounds are given together with a brief analysis of their structures. In the case of L = XeF2 the influence of the properties of the cation and the anion on the structural diversity of these coordination compounds is discussed. A brief analysis of their Raman spectra is also given. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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