Hydrothermal synthesis, characterization and photoluminescence property of a novel indium phosphate with 3D supramolecular structure
| Autor: | Hongwei Ma, Shufei Jiao, Jianshu Song, Fan Gao, Liangliang Huang, Yansong Jiang |
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| Rok vydání: | 2017 |
| Předmět: |
Photoluminescence
Chemistry Ligand Organic Chemistry Inorganic chemistry Supramolecular chemistry Infrared spectroscopy 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Biochemistry Hydrothermal circulation 0104 chemical sciences Indium phosphate Characterization (materials science) Inorganic Chemistry Hydrothermal synthesis 0210 nano-technology Nuclear chemistry |
| DOI: | 10.6084/m9.figshare.5325346 |
| Popis: | A one-dimensional chained indium phosphate In(H2PO4)(HPO4)(C10N2H8) (1) was synthesized under hydrothermal condition using 2,2′-bipyridine as a ligand and characterized by IR spectroscopy, ICP and elemental analyses, powder and single crystal X-ray diffraction analyses. Compound 1 crystallizes in the triclinic system, space group P-1. The connection of In-centered octahedra (InO4N2) and P-centered tetrahedra ({PO3(OH)} and {PO2(OH)2}) constructs a new type of 1D chained structure with In/P ratio of 1/3. Interestingly, H2PO4 tetrahedron and 2,2′-bipyridine ligands "hanging" in the chain by bridging oxygen atoms and nitrogen atoms bond to the central In atoms. It is noted that the adjacent chains are stably packed together and the final structure exhibits interesting three-dimensional (3D) supramolecular array via π–π interactions of the 2,2′-bipyridine groups and hydrogen-bond interactions. Additionally, compound 1 shows strong photoluminescence property in the solid state at room temperature. |
| Databáze: | OpenAIRE |
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