Bicatalytic Allylation–Cross-Metathesis Reactions as γ-Carbonyl Cation Equivalents

Autor:	Jake R. Henkie, James R. Green, Sugadar Dhaliwal
Rok vydání:	2012
Předmět:	Chemistry Organic Chemistry Salt metathesis reaction Organic chemistry indium metathesis Metathesis allylation umpolung Biochemistry Biophysics and Structural Biology electrophilic aromatic substitution
Zdroj:	Chemistry and Biochemistry Publications
ISSN:	1437-2096 0936-5214
DOI:	10.1055/s-0032-1317045
Popis:	The products corresponding to the reactions of arenes and γ-carbonyl cations may be obtained by a one-pot, bicatalytic process involving InCl3-catalyzed arene allylation and cross metathesis with electron-deficient alkenes. The process is successful with electronically neutral and electron-rich arenes, and modestly Lewis basic donor groups are tolerated with an increase in InCl3 loading from 10 mol% to 15 mol%, and in one case, 20 mol%.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4a6324a8cdddb3d06b15672cebe132b4 https://doi.org/10.1055/s-0032-1317045 Zobrazit plný text záznamu