Structural Study of Three Isomers of Tm@C82 by 13C NMR Spectroscopy

Autor:	Yoko Miyake, Norio Ozawa, Isao Ikemoto, Yohji Achiba, Hiroyuki Nishikawa, Takeshi Kodama, Koichi Sakaguchi, Koichi Kikuchi
Rok vydání:	2002
Předmět:	chemistry.chemical_classification Crystallography Colloid and Surface Chemistry 13c nmr spectroscopy Chemistry Stereochemistry General Chemistry Carbon-13 NMR Biochemistry Catalysis Spectral line Divalent
Zdroj:	Journal of the American Chemical Society. 124:1452-1455
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja005839t
Popis:	The (13)C NMR spectra were measured for three isomers of Tm@C(82), which is one of the divalent metallofullerenes. The molecular symmetries were determined for each isomer: isomer I has C(s) symmetry, isomer II has C(2) symmetry, and isomer III has C(2v) symmetry. Moreover the cage structure of Tm@C(82)(III) was found to be C(82)(9). As a result, it was revealed that Tm@C(82)(III) has a cage identical to that of La@C(82), which is one of the trivalent metallofullerenes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4a44f9bc25999b132a07fe00dbd6b877 https://doi.org/10.1021/ja005839t Zobrazit plný text záznamu