Determination of kanamycin using a molecularly imprinted SPR sensor
| Autor: | Cuicui Zhu, Jie Zhou, Shuhua Zhu, Changbao Chen, Lili Zhang, Minglin Wang, Pengpeng Shang |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Detection limit
Acrylate Chromatography Hydrochloride 010401 analytical chemistry Molecularly imprinted polymer Kanamycin 02 engineering and technology General Medicine Polyethylene glycol Surface Plasmon Resonance 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Analytical Chemistry chemistry.chemical_compound chemistry Linear range Limit of Detection medicine 0210 nano-technology Selectivity Food Science medicine.drug |
| Zdroj: | Food Chemistry. 266:170-174 |
| ISSN: | 0308-8146 |
| Popis: | A kanamycin molecular imprinted SPR sensor was prepared with 4-vinylbenzeneboronic acid as the functional monomer, polyethylene glycol acrylate and 2,2′-azo isobutyl amidine hydrochloride as the crosslinker and the initiator, respectively. Under optimum conditions, the response performance of the imprinted SPR sensor to kanamycin was evaluated. The imprinted sensor had a better imprinting effect and selectivity for kanamycin than the non-imprinted one. The linear range of imprinted sensor for kanamycin was from 1.0 × 10−7 to 1.0 × 10−5 mol/L (R2 = 0.9941). Based on a signal-to-noise ratio of 3, the detection limits of kanamycin were 4.33 × 10−8 mol/L for milk powder and 1.20 × 10−8 mol/L for honey, with the RSD as 1.18% and 0.31%, respectively. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect