Plasmonic Temperature-Programmed Desorption
| Autor: | Ferry Anggoro Ardy Nugroho, Christoph Langhammer, Colin J. Murphy, Lars Hellberg, Hanna Härelind |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Materials science
Letter Thermal desorption spectroscopy Mechanical Engineering Nanoparticle metals Bioengineering 02 engineering and technology General Chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics Mass spectrometry Signal plasmonic sensing Adsorption temperature-programmed desorption Chemical physics adsorption Desorption Molecule General Materials Science nanoparticles molecules 0210 nano-technology Plasmon |
| Zdroj: | Nano Letters |
| ISSN: | 1530-6984 |
| DOI: | 10.1021/acs.nanolett.0c03733 |
| Popis: | Temperature-programmed desorption (TPD) allows for the determination of the bonding strength and coverage of molecular mono- or multilayers on a surface and is widely used in surface science. In its traditional form using a mass spectrometric readout, this information is derived indirectly by analysis of resulting desorption peaks. This is problematic because the mass spectrometer signal not only originates from the sample surface but also potentially from other surfaces in the measurement chamber. As a complementary alternative, we introduce plasmonic TPD, which directly measures the surface coverage of molecular species adsorbed on metal nanoparticles at ultrahigh vacuum conditions. Using the examples of methanol and benzene on Au nanoparticle surfaces, the method can resolve all relevant features in the submonolayer and multilayer regimes. Furthermore, it enables the study of two types of nanoparticles simultaneously, which is challenging in a traditional TPD experiment, as we demonstrate specifically for Au and Ag. |
| Databáze: | OpenAIRE |
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