Synthesis of nanosized TiO2 particles in reverse micelle systems and their photocatalytic activity for degradation of toluene in gas phase

Autor: Teruhisa Ohno, Takayuki Fukahori, Ryoji Inaba, Masato Hamamoto
Rok vydání: 2006
Předmět:
Zdroj: Journal of Molecular Catalysis A: Chemical. 260:247-254
ISSN: 1381-1169
DOI: 10.1016/j.molcata.2006.06.053
Popis: Nanosized pure TiO 2 particles with high crystallinity and large surface area were prepared by hydrolysis of tetrabutyl titanate in water/Triton X-100/isooctane reverse micelle solutions as reaction media followed by hydrothermal treatment to improve crystallinity. The prepared TiO 2 nanoparticles were characterized by XRD, BET, TGA, FT-IR and TEM. The size of ultrafine particles was controlled by changing the water content of the reverse micelle solution. The TiO 2 particles showed monodispersity, large surface area and high degrees of crystallinity and thermostability. The photocatalytic activity of the TiO 2 particles was evaluated by decomposition of toluene in the gas phase. The activity of the TiO 2 nanoparticles was higher than that of commercially available anatase fine particles, such as ST-01, which is one of the most active photocatalysts for degradation of organic compounds in the gas phase.
Databáze: OpenAIRE