| Autor: |
Qiang Lin, Qian-Ying Yang, Tao Wu, Xiao-Wei Qi, Xiaopeng Zhang, Lili Wang, Zaifeng Shi, Zhang Dashuai |
| Rok vydání: |
2018 |
| Předmět: |
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| Zdroj: |
Dalton transactions (Cambridge, England : 2003). 47(30) |
| ISSN: |
1477-9234 |
| Popis: |
Circularly polarized luminescence (CPL) activity switched by PtPt interaction is disclosed in two couples of dinuclear Pt(ii) complex enantiomers. Upon varying the length of the bridging ligand, intramolecular metal-metal interaction manipulation is achieved as evidenced from crystal structures. Complex (-)-1 exhibiting strong PtPt interaction displays red phosphorescence with a maximum peak at 638 nm, while complex (-)-2 exhibiting weak PtPt interaction displays green phosphorescence with a maximum peak at 530 nm. The observed CPL was opposite in sign for the two complexes. TD-DFT simulations further confirmed the influence of the PtPt distance on the difference in the electronic optical activities. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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