An Improved Synthesis of N-Isocyanoiminotriphenylphosphorane and Its Use in the Preparation of Diazoketones

Autor:	Zhiguo Jake Song, Gary Javadi, Matthew M. Bio
Rok vydání:	2005
Předmět:	chemistry.chemical_compound Chemistry Diazomethane Reagent Organic Chemistry Organic chemistry General Medicine Catalysis
Zdroj:	ChemInform. 36
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200521181
Popis:	An improved synthesis of N-isocyanoiminotriphenylphosphorane is reported. This reagent is a safe, stable, solid alternative to diazomethane and TMS-diazomethane in the Arndt-Eistert synthesis of diazoketones.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::491acf129b4a40c6b67172ad30af585d https://doi.org/10.1002/chin.200521181 Zobrazit plný text záznamu Plný text