Synthesis of functionalized furans via gold(I)-catalyzed Claisen-type rearrangement
| Autor: | Florin M. Istrate, Fabien Gagosz |
|---|---|
| Přispěvatelé: | Laboratoire de synthèse organique (DCSO), École polytechnique (X)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: |
Reaction mechanism
Molecular Structure 010405 organic chemistry Concerted reaction Chemistry [CHIM.ORGA]Chemical Sciences/Organic chemistry Organic Chemistry Stereoisomerism Ether 010402 general chemistry 01 natural sciences Chemical synthesis Combinatorial chemistry Catalysis 0104 chemical sciences Claisen rearrangement chemistry.chemical_compound Cyclization Organic chemistry Gold Furans Selectivity Ethers |
| Zdroj: | Journal of Organic Chemistry Journal of Organic Chemistry, American Chemical Society, 2008, 73 (2), pp.730-733. ⟨10.1021/jo7022685⟩ |
| ISSN: | 0022-3263 1520-6904 |
| DOI: | 10.1021/jo7022685⟩ |
| Popis: | International audience; (Chemical Equation Presented) Gold(I)-catalyzed cyclization of pentenynyl allyl ethers allows the rapid construction of functionalized furans. The concerted oxy-Claisen-type mechanism induces a complete selectivity of the process and allows the easy formation of quaternary centers. © 2008 American Chemical Society. |
| Databáze: | OpenAIRE |
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