Elastic properties of single crystal Bi12SiO20 as a function of pressure and temperature and acoustic attenuation effects in Bi12MO20 (M= Si, Ge and Ti)
| Autor: | Steffen Ganschow, Björn Winkler, Leonore Wiehl, Hans J. Reichmann, I. Alencar, Lkhamsuren Bayarjargal, Eiken Haussühl, Christian Hirschle, Alexandra Friedrich, Jürgen Schreuer |
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| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
Resonant ultrasound spectroscopy
Phase transition Materials science Polymers and Plastics Standard molar entropy Enthalpy Metals and Alloys Thermodynamics Heat capacity Thermal expansion Surfaces Coatings and Films Electronic Optical and Magnetic Materials Biomaterials symbols.namesake symbols Debye model Debye |
| Zdroj: | Materials Research Express |
| Popis: | A comprehensive study of sillenite Bi12SiO20 single-crystal properties, including elastic stiffness and piezoelectric coefficients, dielectric permittivity, thermal expansion and molar heat capacity, is presented. Brillouin-interferometry measurements (up to 27 GPa), which were performed at high pressures for the first time, and ab initio calculations based on density functional theory (up to 50 GPa) show the stability of the sillenite structure in the investigated pressure range, in agreement with previous studies. Elastic stiffness coefficients c 11 and c 12 are found to increase continuously with pressure while c 44 increases slightly for lower pressures and remains nearly constant above 15 GPa. Heat-capacity measurements were performed with a quasi-adiabatic calorimeter employing the relaxation method between 2 K and 395 K. No phase transition could be observed in this temperature interval. Standard molar entropy, enthalpy change and Debye temperature are extracted from the data. The results are found to be roughly half of the previous values reported in the literature. The discrepancy is attributed to the overestimation of the Debye temperature which was extracted from high-temperature data. Additionally, Debye temperatures obtained from mean sound velocities derived by Voigt-Reuss averaging are in agreement with our heat-capacity results. Finally, a complete set of electromechanical coefficients was deduced from the application of resonant ultrasound spectroscopy between 103 K and 733 K. No discontinuities in the temperature dependence of the coefficients are observed. High-temperature (up to 1100 K) resonant ultrasound spectra recorded for Bi12 MO20 crystals revealed strong and reversible acoustic dissipation effects at 870 K, 960 K and 550 K for M = Si, Ge and Ti, respectively. Resonances with small contributions from the elastic shear stiffness c 44 and the piezoelectric stress coefficient e 123 are almost unaffected by this dissipation. |
| Databáze: | OpenAIRE |
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