Suppressing Electron Back‐Donation for a Highly CO‐tolerant Fuel Cell Anode Catalyst via Cobalt Modulation

Autor: Yu Yang, Fei‐Yue Gao, Xiao‐Long Zhang, Shuai Qin, Li‐Rong Zheng, Ye‐Hua Wang, Jie Liao, Qing Yang, Min‐Rui Gao
Rok vydání: 2022
Předmět:
Zdroj: Angewandte Chemie. 134
ISSN: 1521-3757
0044-8249
Popis: Platinum on carbon (Pt/C) catalyst is commercially adopted in fuel cells but it undergoes formidable active-site poisoning by carbon monoxide (CO). In particular, given the sluggish kinetics of hydrogen oxidation reaction (HOR) in anion-exchange membrane fuel cell (AEMFC), the issues of Pt poisoning and slow rate would combine mutually, notably worsening the device performances. Here we overcome these challenges through incorporating cobalt (Co) into molybdenum-nickel alloy (MoNi
Databáze: OpenAIRE