| Autor: |
Ridha Zerdoumi, Oksana Matselko, Leonard Rößner, Bidushi Sarkar, Yuri Grin, Marc Armbrüster |
| Rok vydání: |
2022 |
| Předmět: |
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| Zdroj: |
Journal of the American Chemical Society. 144(18) |
| ISSN: |
1520-5126 |
| Popis: |
Efficient development of catalytic materials requires knowledge of the decisive parameters defining the catalytic properties. In multicomponent metallic catalysts, these are categorized as electronic and geometric effects, yet they are strongly interrelated. A systematic disentanglement can be achieved by fixing one parameter while altering the other, which becomes possible through the substitution in isostructural intermetallic compounds. This approach enables the evaluation of electronic or geometric contributions both individually and combined. Herein, this is achieved by substitution of indium (three valence electrons) with tin (four valence electrons) in the series In |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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