An Efficient Catalytic System for the Hydrogenation of Quinolines
| Autor: | Sheng-Mei Lu, Xiu-Wen Han, Yong-Gui Zhou |
|---|---|
| Rok vydání: | 2007 |
| Předmět: |
Organic Chemistry
Quinoline Noyori asymmetric hydrogenation chemistry.chemical_element General Medicine Iodine Biochemistry Medicinal chemistry Catalysis Inorganic Chemistry chemistry.chemical_compound chemistry Hydrogenation reaction Materials Chemistry Organic chemistry Reactivity (chemistry) Physical and Theoretical Chemistry |
| Zdroj: | ChemInform. 38 |
| ISSN: | 1522-2667 0931-7597 |
| DOI: | 10.1002/chin.200742142 |
| Popis: | A new catalytic system ([Ru(p-cymene)Cl-2](2)/I-2) has been developed for the hydrogenation of quinoline derivatives with high reactivity. For the 2-methyl-quinoline, the hydrogenation reaction can proceed smoothly at an S/C of 20,000/1 with complete conversion. The iodine additive is important for the reactivity. (C) 2007 Elsevier B.V. All rights reserved. |
| Databáze: | OpenAIRE |
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