1,4,7-Triazacyclononane Ligands Bearing Tertiary Alkyl Nitrogen Substituents

Autor:	John Bacsa, Arumugam Thangavel, Marika Wieliczko, Christopher C. Scarborough
Rok vydání:	2013
Předmět:	chemistry.chemical_classification Steric effects Bearing (mechanical) Stereochemistry Ligand chemistry.chemical_element Medicinal chemistry Nitrogen law.invention Inorganic Chemistry chemistry law Physical and Theoretical Chemistry Alkyl
Zdroj:	Inorganic Chemistry. 52:13282-13287
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic402626p
Popis:	The first synthesis of 1,4,7-tri-tert-butyl-1,4,7-triazacyclononane ((t)Bu3tacn) and its adamantyl analog Ad3tacn are described. Cr(II), Mn(II), Fe(II), Co(II), Ni(II), and Cu(I) compounds of (t)Bu3tacn are reported: the steric properties of this ligand enforce four-coordinate geometries except in the case of five-coordinate Cr(II), enabling design of pseudotetrahedral compounds bearing this tridentate redox-inert ancillary ligand.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::47dd09f7d207b624f7e5f76dd9875ca7 https://doi.org/10.1021/ic402626p Zobrazit plný text záznamu