CO_{2}$-assisted synthesis of non-symmetric alpha-diketones directly from aldehydes via C-C bond formation

Autor:	Pradipbhai Hirapara, Shoubhik Das, Daniel Riemer, Jignesh Gajera, Nabanita Hazra, Markus Finger
Jazyk:	angličtina
Rok vydání:	2017
Předmět:	010405 organic chemistry Chemistry Non symmetric Bond formation 010402 general chemistry 01 natural sciences Pollution 0104 chemical sciences Catalysis Computational chemistry Environmental Chemistry Organic chemistry Engineering sciences. Technology
Zdroj:	Green chemistry : cutting-edge research for a greener sustainable future
ISSN:	1463-9262
Popis:	CO2-assisted various symmetric and non-symmetric alpha-diketones have been synthesized directly from the corresponding aldehydes using transition metal-free catalysts. This method can even be applied to synthesize pharmaceuticals directly from aldehydes. The crucial role of CO2 has been investigated in detail and the mechanism is proposed on the basis of experiments and DFT calculations.
Databáze:	OpenAIRE
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