The Ethylene–Carbon Dioxide Complex and the Double Rotor Model
| Autor: | Nasser Moazzen-Ahmadi, A. R. W. McKellar |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
Jet (fluid)
Ethylene 010304 chemical physics Chemistry Rotor (electric) Infrared Spectrum (functional analysis) FOS: Physical sciences 010402 general chemistry 01 natural sciences Molecular physics Symmetry (physics) 3. Good health 0104 chemical sciences law.invention chemistry.chemical_compound law 0103 physical sciences Perpendicular Supersonic speed Physics - Atomic and Molecular Clusters Physics::Chemical Physics Physical and Theoretical Chemistry Atomic and Molecular Clusters (physics.atm-clus) |
| Zdroj: | The Journal of Physical Chemistry A. 124:684-689 |
| ISSN: | 1520-5215 1089-5639 |
| Popis: | The infrared spectrum of the weakly-bound C2H4-CO2 complex is investigated in the region of the nu3 fundamental band of CO2 (~2350 cm-1), using a tunable OPO laser source to probe a pulsed supersonic slit jet expansion. The spacing of the various K-subbands in this perpendicular spectrum is very irregular, and the pattern of irregularity is quite different from that observed previously in another C2H4-CO2 band by Bemish et al. [J. Chem. Phys. 103, 7788 (1995)]. But by allowing for the different symmetry of the nu3 (CO2) upper vibrational state, both results can be strikingly well explained using the 'double internal rotor' model as described by Bemish et al. 27 page and 6 figures |
| Databáze: | OpenAIRE |
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