Recent Advances in Ruthenium-Catalyzed Carbene/Alkyne Metathesis (CAM) Transformations
| Autor: | Damián Padín, CDMF FAPESP, Jesús A. Varela, Carlos Saa |
|---|---|
| Přispěvatelé: | Universidade de Santiago de Compostela. Departamento de Química Orgánica |
| Rok vydání: | 2020 |
| Předmět: |
Vinyl ruthenium carbenes
010405 organic chemistry Organic Chemistry chemistry.chemical_element Metathesis Heterocycles 010402 general chemistry 01 natural sciences Chemical synthesis Combinatorial chemistry 0104 chemical sciences Catalysis Ruthenium chemistry.chemical_compound chemistry Cyclization Alkyne metathesis Carbenes Stereoselectivity Carbene Alkynyl derivatives |
| Zdroj: | Minerva: Repositorio Institucional de la Universidad de Santiago de Compostela Universidad de Santiago de Compostela (USC) Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela instname |
| Popis: | NOTICE: This is the peer reviewed version of the following article: Padín, D., Varela, J. A., Saá, C. (2020). Recent Advances in Ruthenium-Catalyzed Carbene/Alkyne Metathesis (CAM) Transformations. Synlett, 31, 12, 1147-1157. [doi: 10.1055/s-0039-1690861]. This article may be used for non-commercial purposes in accordance with Thieme Terms and Conditions for self-archiving Carbene intermediates have shown versatile applications in modern synthetic chemistry. Catalytic ruthenium carbene/alkyne metathesis (CAM) with readily available substrates renders an efficient procedure for the in situ generation of ruthenium vinyl carbene intermediates. Here, recent advances in synthetic applications of ruthenium-catalyzed carbene/alkyne metathesis (CAM) are highlighted. This work has received financial support from MINECO (project CTQ2017-87939R and ORFEO-CINQA network RED2018-102387-T), the Xunta de Galicia (project ED431C 2018/04 and Centro singular de investigación de Galicia accreditation 2019-2022, ED431G 2019/03) and the European Union (European Regional Development Fund – ERDF). D. P. thanks MEC for a predoctoral FPU fellowship (FPU15/02132) SI |
| Databáze: | OpenAIRE |
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