Tantalum, easy as Pi: understanding differences in metal-imido bonding towards improving Ta/Nb separations

Autor: Alexander B. Weberg, Subhajyoti Chaudhuri, Thibault Cheisson, Christian Uruburo, Ekaterina Lapsheva, Pragati Pandey, Michael R. Gau, Patrick J. Carroll, George C. Schatz, Eric J. Schelter
Rok vydání: 2022
Předmět:
Zdroj: Chemical science. 13(23)
ISSN: 2041-6520
Popis: The separation and purification of niobium and tantalum, which co-occur in natural sources, is difficult due to their similar physical and chemical properties. The current industrial method for separating Ta/Nb mixtures uses an energy-intensive process with caustic and toxic conditions. It is of interest to develop alternative, fundamental methodologies for the purification of these technologically important metals that improve upon their environmental impact. Herein, we introduce new Ta/Nb imido compounds: M(
Databáze: OpenAIRE