The Role of Temperature and Adsorbate on Negative Gas Adsorption in the Mesoporous Metal-Organic Framework DUT-49
| Autor: | Stefan Kaskel, Nico Grimm, Dirk Wallacher, Daniel D. Többens, François-Xavier Coudert, Irena Senkovska, Volodymyr Bon, Jack D. Evans, Simon Krause |
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| Přispěvatelé: | Technische Universität Dresden = Dresden University of Technology (TU Dresden), Stratingh Institute for Chemistry, University of Groningen [Groningen], Institut de Recherche de Chimie Paris (IRCP), Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Centre National de la Recherche Scientifique (CNRS)-Ministère de la Culture (MC), Helmholtz Centre for Materials and Energy (HZB) |
| Rok vydání: | 2020 |
| Předmět: |
[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry
[CHIM]Chemical Sciences [CHIM.MATE]Chemical Sciences/Material chemistry 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 0210 nano-technology 01 natural sciences ComputingMilieux_MISCELLANEOUS 0104 chemical sciences |
| Zdroj: | Faraday Discussions Faraday Discussions, Royal Society of Chemistry, 2020, ⟨10.1039/D0FD00013B⟩ |
| ISSN: | 1359-6640 1364-5498 |
| DOI: | 10.26434/chemrxiv.11733408.v1 |
| Popis: | In this contribution, we present an extensive investigation of adsorption of a range of different gases at various temperatures in DUT-49, a metal-organic framework which features a negative gas adsorption (NGA) transition. Adsorption experiments at temperatures ranging from 21 to 308 K, were used to identify, for each guest, a critical temperature range in which NGA occurs. The experimental results were complemented by molecular simulations that rationalize the absence of NGA at elevated temperatures and the non-monotonic behavior observed upon temperature decrease. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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