Multiphotocatalyst Cascades: From Furans to Fused Butyrolactones and Substituted Cyclopentanones

Autor:	Lamprini-Panagiota Apostolina, Artemis Bosveli, Antonia Profyllidou, Tamsyn Montagnon, Vasileios Tsopanakis, Maria Kaloumenou, Dimitris Kalaitzakis, Georgios Vassilikogiannakis
Rok vydání:	2022
Předmět:	Organic Chemistry Physical and Theoretical Chemistry Furans Biochemistry
Zdroj:	Organic Letters. 24:8786-8790
ISSN:	1523-7052 1523-7060
DOI:	10.1021/acs.orglett.2c03513
Popis:	High value oxygenated polycycles have been rapidly and efficiently accessed from simple precursors in one pot processes. The reported methodology relies on a new and mild method for butenolide synthesis mediated by thiols. The initial photooxygenation and butenolide synthesis have been merged with subsequent photoredox reactions to achieve rare dual-photocatalyst cascades affording various fused butyrolactones. Ground state Lewis acid activity for methylene blue has been unveiled and then exploited in the synthesis of substituted cyclopentanones.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::46b26f4c7d7c4f23d75a89b1c06c1367 https://doi.org/10.1021/acs.orglett.2c03513 Zobrazit plný text záznamu