Life cycle assessment of emerging Ni–Co hydroxide charge storage electrodes: impact of graphene oxide and synthesis route

Autor: Edis Glogic, Guido Sonnemann, Steven B. Young, Liliane Guerlou-Demourgues, Alberto Adán-Más, Maria de Fátima Montemor
Přispěvatelé: Institut des Sciences Moléculaires (ISM), Université Montesquieu - Bordeaux 4-Université Sciences et Technologies - Bordeaux 1-École Nationale Supérieure de Chimie et de Physique de Bordeaux (ENSCPB)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), School of Environment, Enterprise and Development [Waterloo] (SEED), University of Waterloo [Waterloo], Centro de Quimica Estrutural (CQE), Instituto Superior Técnico, Universidade Técnica de Lisboa (IST), Institut de Chimie de la Matière Condensée de Bordeaux (ICMCB), Université de Bordeaux (UB)-Institut Polytechnique de Bordeaux-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Réseau sur le stockage électrochimique de l'énergie (RS2E), Université de Picardie Jules Verne (UPJV)-Institut de Chimie du CNRS (INC)-Aix Marseille Université (AMU)-Université de Pau et des Pays de l'Adour (UPPA)-Université de Nantes (UN)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS)-Sorbonne Université (SU)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Collège de France (CdF (institution))-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Université Grenoble Alpes (UGA)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM), This work was financially supported by the Lebanese Council of Scientific Research (CNRSL), the Lebanese University and the AZM & SAADE Association., Université Montesquieu - Bordeaux 4-Université Sciences et Technologies - Bordeaux 1 (UB)-École Nationale Supérieure de Chimie et de Physique de Bordeaux (ENSCPB)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Université de Nantes (UN)-Aix Marseille Université (AMU)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Collège de France (CdF (institution))-Université de Picardie Jules Verne (UPJV)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université de Pau et des Pays de l'Adour (UPPA)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Université Grenoble Alpes (UGA)
Jazyk: angličtina
Rok vydání: 2019
Předmět:
Zdroj: RSC Advances
RSC Advances, Royal Society of Chemistry, 2019, 9 (33), pp.18853-18862. ⟨10.1039/C9RA02720C⟩
RSC Advances, 2019, 9 (33), pp.18853-18862. ⟨10.1039/C9RA02720C⟩
ISSN: 2046-2069
Popis: International audience; Decoupling energy supply from fossil fuels through electrification and sustainable energy management requires efficient and environmentally low-impact energy storage technologies. Potential candidates are charge storage electrodes that combine nickel and cobalt hydroxides with reduced graphene oxide (rGO) designed to achieve high-energy, high-power density and long cycling lifetimes. An early eco-efficiency analysis of these electrodes seeks to examine the impacts of materials and processes used in the synthesis, specifically while focusing on the use of rGO. The emerging electrodes synthesized by means of electrodeposition, are further compared with electrodes obtained by an alternative synthesis route involving co-precipitation. Life cycle assessment (LCA) method was applied to compare a baseline nickel–cobalt hydroxide electrode (NCED), the focal electrode integrating rGO (NCED-rGO), and the benchmark co-precipitated electrode (NCCP), for delivering the charge of 1000 mA h. Contribution analysis reveals that the main environmental hotspots in the synthesis of the NCED-rGO are the use of electricity for potentiostat, ethanol for cleaning, and rGO. Results of comparison show significantly better performance of NCED-rGO in comparison to NCED across all impact categories, suggesting that improved functionalities by addition of rGO outweigh added impacts of the use of material itself. NCED-rGO is more impactful than NCCP except for the indicators of cumulative energy demand, climate change, and fossil depletion. To produce a functional equivalent for the three electrodes, total cumulative energy use was estimated to be 78 W h for NCED, 25 W h for NCED-rGO, and 35 W h for NCCP. Sensitivity analysis explores the significance of rGO efficiency uptake on the relative comparison with NCCP, and potential impact of rGO on the category of freshwater ecotoxicity given absence of removal from the process effluent. Scenario analysis further shows relative performance of the electrodes at the range of alternative functional parameters of current density and lifetime. Lastly, the environmental performance of NCED-rGO electrodes is discussed in regard to technology readiness level and opportunities for design improvements.
Databáze: OpenAIRE
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