Concerted proton migration along short hydrogen bonded water bridges in bipyridine-water clusters

Autor:	Alexey S. Zatula, Einar Uggerud, Mauritz Johan Ryding
Rok vydání:	2012
Předmět:	Bipyridine chemistry.chemical_compound Crystallography Ionic clusters chemistry Proton Hydrogen Stereochemistry General Physics and Astronomy chemistry.chemical_element Physical and Theoretical Chemistry Nitrogen
Zdroj:	Physical chemistry chemical physics : PCCP. 14(40)
ISSN:	1463-9084
Popis:	The outcome of reactions between D(2)O and size-selected ionic clusters of the type MH(+)(H(2)O)(n) (M = bipyridine, n = 1-30) shows that H-D-exchange is significantly higher for 2,2'-bipyridines than for 4,4'-bipyridines. This gives strong support for the idea that the existence of short water wires between the two nitrogen sites is essential to proton migration in water clusters containing basic sites.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::463980bf3b6617aa2268634461c93a8e https://pubmed.ncbi.nlm.nih.gov/22990649 Zobrazit plný text záznamu