Intermolecular Contact-Tuned Magnetic Nature in One-Dimensional 3d−5d Bimetallic Systems: From a Metamagnet to a Single-Chain Magnet
| Autor: | Seok Woo Choi, Eui Kwan Koh, Jung Hee Yoon, Hyoung Chan Kim, Chang Seop Hong, Hyun Young Kwak |
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| Rok vydání: | 2008 |
| Předmět: |
Models
Molecular chemistry.chemical_classification Manganese Cyanides Condensed matter physics Intermolecular force Polymer Single chain Naphthalenes Tungsten Inorganic Chemistry Magnetics Crystallography 2 2'-Dipyridyl chemistry Cyclohexanes Magnet Organometallic Compounds Anisotropy Amines Physical and Theoretical Chemistry Bimetallic strip |
| Zdroj: | Inorganic Chemistry. 47:10214-10216 |
| ISSN: | 1520-510X 0020-1669 |
| DOI: | 10.1021/ic801699p |
| Popis: | Assembling [W(CN) 6(bpy)] (-) and magnetic anisotropic Mn Schiff bases produced two Mn (III)(3d)-W (V)(5d) bimetallic chains. Modulation of the types and degrees of interchain pi-pi interactions in the one-dimensional coordination polymers leads to the variation of the magnetic behavior from a metamagnetic character to a single-chain magnet property. |
| Databáze: | OpenAIRE |
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