Synthesis of 1-oxadecalins from anisole promoted by tungsten
| Autor: | William H. Myers, Michal Sabat, W. Dean Harman, Rebecca J. Salomon, Edward C. Lis |
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| Rok vydání: | 2008 |
| Předmět: |
Nucleophilic addition
Acrolein chemistry.chemical_element Protonation General Chemistry Tungsten Anisoles Naphthalenes Anisole Biochemistry Catalysis Stereocenter chemistry.chemical_compound Bridged Bicyclo Compounds Colloid and Surface Chemistry chemistry Nucleophile Methyl vinyl ketone Organometallic Compounds Organic chemistry |
| Zdroj: | Journal of the American Chemical Society. 130(37) |
| ISSN: | 1520-5126 |
| Popis: | The complex TpW(NO)(PMe3)(eta(2)-anisole) is combined with acrolein or methyl vinyl ketone and various nucleophiles to generate novel chromen complexes. These complexes may be further elaborated by protonation and nucleophilic addition to generate chroman analogues with increased saturation and stereocenters. Treatment with various oxidants effects the decomplexation of the chromen. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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