Anionic Extraction for Efficient Recovery of Biobased 2,3-Butanediol-A Platform for Bulk and Fine Chemicals
| Autor: | Jochen Förster, Lars M. Blank, Irina Delidovich, Till Tiso, Benedikt Heyman, Paula Gaspar, Jochen Büchs, Peter Drabo, Eda Sarikaya |
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| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: |
Green chemistry
Ketone General Chemical Engineering Chemical Fractionation 010402 general chemistry 01 natural sciences Catalysis chemistry.chemical_compound 2 3-Butanediol Environmental Chemistry Organic chemistry General Materials Science SDG 7 - Affordable and Clean Energy Butylene Glycols chemistry.chemical_classification Aqueous solution Chromatography 010405 organic chemistry Extraction (chemistry) Water food and beverages Sulfuric acid Boronic Acids 0104 chemical sciences General Energy chemistry Biocatalysis Fermentation |
| Zdroj: | Drabo, P, Tiso, T, Heyman, B, Sarikaya, E, Gaspar, P, Förster, J, Büchs, J, Blank, L M & Delidovich, I 2017, ' Anionic Extraction for Efficient Recovery of Biobased 2,3-Butanediol-A Platform for Bulk and Fine Chemicals ', ChemSusChem , vol. 10, no. 16, pp. 3252-3259 . https://doi.org/10.1002/cssc.201700899 |
| DOI: | 10.1002/cssc.201700899 |
| Popis: | 2,3-Butanediol (BDO) presents a promising platform molecule for the synthesis of basic and fine chemicals. Biotechnological production of BDO from renewable resources with living microbes enables high concentrations in the fermentation broth. The recovery of high-boiling BDO from an aqueous fermentation broth presents a subsequent challenge. A method is proposed for BDO isolation based on reversible complexation with phenylboronate in an anionic complex. BDO can be recovered by back-extraction into an acidic solution. The composition of the extracted species was determined by NMR spectroscopy, MS, and GC-MS methods. The conditions of extraction and back-extraction were optimized by using commercial BDO and finally applied to different fermentation broths. Up to 72-93 % BDO can be extracted and up to 80-90 % can be back-extracted under the optimized conditions. Purified bio-BDO was used in the presence of sulfuric acid for the synthesis of methyl ethyl ketone, an established organic solvent and discussed tailor-made biofuel. |
| Databáze: | OpenAIRE |
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