Slow epimerization of stereochemically rigid diastereomers of the equatorially substituted cluster [Os3H2(μ3-S)(CO)8{(S)-PhCHMeNH2}]

Autor:	Caroline S. Forth, Jade O. Prince, Antony J. Deeming, Graeme Hogarth, Jonathan W. Steed, David Markham
Rok vydání:	2002
Předmět:	Ligand Chemistry Stereochemistry Metals and Alloys Diastereomer General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Metal visual_art Materials Chemistry Ceramics and Composites Cluster (physics) visual_art.visual_art_medium Epimer
Zdroj:	Chem. Commun.. :2230-2231
ISSN:	1364-548X 1359-7345
Popis:	Turnstile rotation is suppressed in the equatorially substituted cluster [Os3(mu-H)2(mu 3-S)(CO)8((S)-PhCHMeNH2)] which was separated by HPLC into two diastereomers which do not interconvert at room temperature and epimerize only slowly at 90 degrees C.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::459f24203826def70aa966fbec5ddefa https://doi.org/10.1039/b203611h Zobrazit plný text záznamu